Both 募 (ボ) and 集 (シュウ) are read with their on'yomi. The long vowel for シュウ is important; ぼしゅは a common pronunciation error. It means to openly invite applications, participation, or contributions from many people.
募集は募(ボ)と集(シュウ)の音読みです。集の長音を抜いた「ぼしゅ」は誤りです。広く一般から、人員や参加者、寄付金などを募り集めることを意味します。
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