The correct reading is みつりょう, with both 密 (ミツ) and 漁 (リョウ) using On'yomi. Note that 漁 is read as リョウ in this context (poaching/hunting), not ギョ. 密漁 refers to poaching or illegal fishing.
「密」は「ミツ」、「漁」は「リョウ」と両方とも音読みです。「漁」は「ギョ」とも読みますが、この熟語では「リョウ」です。許可なく魚などを捕獲する違法な漁業です。
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